Abstract

The reactions of Cu(II), Co(II), and Zn(II) terephthalates with hydroxyalkylamines (tris(2-hydroxyethyl)amine, bis(2-hydroxyethyl)amine, tris(hydroxymethyl)aminomethane, and bis(2-hydroxyethyl)aminotris(hydroxymethyl)methane) are studied for the first time. The structures and properties of the synthesized complexes are studied by IR spectroscopy, electronic absorption spectroscopy, mass spectrometry, and elemental and thermal analyses. The structure of the binuclear heteroligand [Cu₂(TEA)₂(Tph)]_n·H₂O complex is studied by single-crystal X-ray diffraction (XRD) (CIF file CCDC no. 2224437).

中文翻译：

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对苯二甲酸 Cu(II)、Co(II) 和 Zn(II) 与羟烷基胺的络合物

摘要

对苯二甲酸铜 (II)、钴 (II) 和锌 (II) 与羟烷基胺（三（2-羟乙基）胺、双（2-羟乙基）胺、三（羟甲基）氨基甲烷和双（2-羟乙基）的反应）首次研究了氨基三（羟甲基）甲烷）。通过红外光谱、电子吸收光谱、质谱、元素分析和热分析研究了合成配合物的结构和性质。通过单晶X射线衍射(XRD)研究了双核异质配体[Cu ₂ (TEA) ₂ (Tph)] _n ·H _{2 O配合物的结构（CIF文件CCDC no. 2224437）。}