Synthesis and Crystal Structure of a Novel Organo-Inorganic Hybrid Borate, K[B5O6(OH)4][B(OH)3]2(H2O)(C10H20O5)2,Glass Physics and Chemistry

当前位置： X-MOL 学术 › Glass Phys. Chem. › 论文详情

Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)

Synthesis and Crystal Structure of a Novel Organo-Inorganic Hybrid Borate, K[B5O6(OH)4][B(OH)3]2(H2O)(C10H20O5)2
Glass Physics and Chemistry ( IF 0.7 ) Pub Date : 2023-11-16 , DOI: 10.1134/s1087659623600485
V. A. Yukhno , D. O. Charkin , S. N. Volkov , L. S. Manelis , A. N. Gosteva , S. M. Aksenov , R. S. Bubnova

Abstract

Crystals of a novel hybrid organo-inorganic borate, K[B₅O₆(OH)₄][B(OH)₃]₂(H₂O)(C₁₀H₂₀O₅)₂ (1), were obtained from aqueous solutions and characterized by single-crystal X-ray diffraction and IR spectroscopy. 1 is triclinic (a = 10.1567(4), b = 11.9941(6), c = 17.1893(9) Å, α = 75.280(4), β = 79.406(4), γ = 88.531(4)°, V = 1990.270369 Å³, SG P-1; R₁ = 0.058). Its structure contains [K(C₁₀H₂₀O₅)₂]⁺ groups which behave as “hydrophobic” templates for the inorganic part comprised of \({{{\text{B}}}_{{\text{5}}}}{{{\text{O}}}_{{\text{6}}}}\left( {{\text{OH}}} \right)_{4}^{ - }\) anions and neutral B(OH)₃ molecules.

更新日期：2023-11-17

点击分享查看原文

点击收藏

阅读更多本刊最新论文本刊介绍/投稿指南

全部期刊列表>>