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Quasi-static piezoelectric strain and recoverable energy at a low biased field in Sr2+ substituted electrostrictive BZT ceramic
Bulletin of Materials Science ( IF 1.8 ) Pub Date : 2023-12-27 , DOI: 10.1007/s12034-023-03083-2
Aditi Manna , D K Kushvaha , S K Rout , B Tiwari , Takeshi Yoshimura

Sr2+ modified perovskite-type polycrystalline BaTi0.9Zr0.1O3 ferroelectric ceramic exhibits high potential to engage in piezoelectric or high energy density storage applications. In this study, the structural, microstructural, electrical, ferroelectric and piezoelectric behaviours have been investigated in detail. The developed material crystallizes in tetragonal phase with a decrease in lattice parameter by substituting Sr2+ ion in the A site. Each composition shows a diffused phase transition, which is a characteristic of the relaxor phase. A significant decrease in phase transition temperature from 99.8°C for x = 0.00 to 50.9°C for x = 0.20 is observed. The large energy density storage capacity for composition x = 0.10 with Wrec ~ 62.18 mJ cm–3 has been observed at a low field, but maximum efficiency η = ~81.46% is observed for x = 0.20. The Sr2+ doped composition with x = 0.10 shows good piezoelectric strain = 0.029% with a small hysteresis loss in SE curve, which makes it suitable for piezoelectric application. The significantly high electrostrictive coefficient Q11 = 0.078 m4 C–2 is observed for composition x = 0.15.



中文翻译:

Sr2+取代电致伸缩BZT陶瓷在低偏置场下的准静态压电应变和可恢复能量

Sr 2+改性钙钛矿型多晶BaTi 0.9 Zr 0.1 O 3铁电陶瓷在压电或高能量密度存储应用中表现出很高的潜力。在这项研究中,详细研究了结构、微观结构、电学、铁电和压电行为。所开发的材料通过在A位取代Sr 2+离子而以四方相结晶,晶格参数降低。每种组合物都显示出扩散相变,这是弛豫相的特征。观察到相变温度从x = 0.00时的 99.8°C 显着降低到x = 0.20 时的 50.9°C。在低场下观察到组合物x = 0.10 的大能量密度存储容量, W rec ~ 62.18 mJ cm –3 ,但在x = 0.20时观察到最大效率η = ~81.46% 。x = 0.10 的Sr 2+掺杂组合物表现出良好的压电应变 = 0.029%,并且SE曲线中的磁滞损耗较小,这使其适合压电应用。对于成分x = 0.15 ,观察到显着高的电致伸缩系数Q 11 = 0.078 m 4 C –2

更新日期:2023-12-28
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