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A solid-state 171Yb NMR-spectroscopic characterization of selected divalent ytterbium intermetallics
Zeitschrift für Naturforschung B ( IF 0.8 ) Pub Date : 2024-01-12 , DOI: 10.1515/znb-2023-0070
Josef Maximilian Gerdes 1 , Lars Schumacher 2 , Michael Ryan Hansen 1 , Rainer Pöttgen 2
Affiliation  

The intermetallic ytterbium compounds YbZnSn, YbPdSn2, YbAuIn2 and their calcium-substituted counterparts Yb0.5Ca0.5ZnSn, Yb0.5Ca0.5PdSn2 and Yb0.5Ca0.5AuIn2 were synthesized by reaction of the elements in sealed tantalum tubes in an induction furnace. The samples were characterized by X-ray powder diffraction. Their static, temperature-dependent solid-state 171Yb NMR spectra exhibit strong positive Knight shifts without any significant temperature dependence. The resonance shifts including anisotropy parameters for the ternary compounds have been determined.

中文翻译:

选定二价镱金属间化合物的固态 171Yb NMR 光谱表征

金属间镱化合物YbZnSn、YbPdSn2, YbAuIn2及其钙取代对应物 Yb0.50.5锌锡、镱0.50.5钯锡2和镱0.50.5金铟2通过感应炉中密封钽管中的元素反应合成。通过X射线粉末衍射对样品进行了表征。它们是静态的、与温度相关的固态171Yb NMR 谱表现出强烈的正奈特位移,没有任何显着的温度依赖性。已经确定了三元化合物的共振位移,包括各向异性参数。
更新日期:2024-01-12
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