Rhenium Cluster Complexes with Polyborohydride Anions, [Re6S8(Me2PzH)6]X (X = B10H10, B12H12),Journal of Structural Chemistry

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Rhenium Cluster Complexes with Polyborohydride Anions, [Re6S8(Me2PzH)6]X (X = B10H10, B12H12)
Journal of Structural Chemistry ( IF 0.8 ) Pub Date : 2024-02-09 , DOI: 10.1134/s0022476624010177
M. P. Davydova , T. S. Sukhikh , M. I. Rakhmanova , K. A. Brylev , A. V. Artem’ev

Abstract

Interaction of [Re₆S₈(Me₂PzH)₆]Br₂ with K₂B₁₀H₁₀ and (Et₃NH)₂B₁₂H₁₂ yields novel [Re₆S₈(Me₂PzH)₆][B₁₀H₁₀] (1) and [Re₆S₈(Me₂PzH)₆][B₁₂H₁₂] (2) hybrid compounds combining [Re₆S₈ (Me₂PzH)₆]²⁺ metal-cluster cations and [B_nH_n]^2– polyborohydride cluster anions (n = 10, 12) in their structure. Crystals of the prepared compounds exhibit an ionic 3D supramolecular structure formed by short H–B⋯H–C contacts. At room temperature, these compounds exhibit red phosphorescence with λ_max = 680 nm (1) and 670 nm (2), respectively.

更新日期：2024-02-09

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