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A Tris-Chelate Nickel Complex of Formylhydrazine: Synthesis and Crystal Structure
Journal of Structural Chemistry ( IF 0.8 ) Pub Date : 2024-03-01 , DOI: 10.1134/s0022476624020136
A. A. Zabolotnyi , O. P. Demidov , S. B. Zaichenko , A. V. Bicherov , N. V. Ter-Oganessian

Abstract

The Ni(FH)3Cl2·H2O complex is prepared by the in situ reaction of formic acid, hydrazine hydrate, and nickel(II) chloride. It is structurally characterized as a tris-chelated complex cation containing chloride anions as counterions and crystallizing in the P21/c centrosymmetric monoclinic space group.



中文翻译:

甲酰肼的三螯合镍配合物:合成和晶体结构

摘要

Ni(FH) 3 Cl 2 ·H 2 O络合物由甲酸、水合肼和氯化镍(II)原位反应制备。其结构特征为含有氯阴离子作为抗衡离子的三螯合络合物阳离子,并在P 2 1 / c中心对称单斜空间群中结晶。

更新日期:2024-03-01
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