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Synthesis and Thermal Properties of Myristic Acid/Nano-TiO2/Carbon Additives Composite Phase Change Materials
International Journal of Thermophysics ( IF 2.2 ) Pub Date : 2024-03-02 , DOI: 10.1007/s10765-024-03346-y
Tingwei Fu , Wenze Wang , Guiyin Fang

A novel composite phase change material, myristic acid (MA)/nano-titanium dioxide (nano-TiO2)/carbon additives, was synthesized via a melt blending method, in which MA serves as phase change material, nano-TiO2 acts as support material, and carbon additives are used as thermally conductive enhancer. A series of leakage tests have shown that MA/nano-TiO2 can maintain shape stability during the phase transition when the content of MA in MA/nano-TiO2 does not exceed 50 %. The FT-IR and XRD results demonstrated that there is no chemical reaction among the various components of the MA/nano-TiO2/carbon additive. When the content of MA is 50 %, the melting temperature of MA/nano-TiO2/carbon additives is about 54 °C and the melting enthalpy is about 80 J·g−1. When the content of all three carbon additives, multiwall carbon nanotubes, graphene, and expanded graphite, is 2.5 %, the corresponding thermal conductivity of MA/nano-TiO2/carbon additives is 0.532 W/(m·K), 1.128 W/(m·K), and 1.382 W/(m·K), respectively. The thermal conductivity of these three types of MA/nano-TiO2/additives is 1.23, 2.62, and 3.21 times that of MA/TiO2, respectively. Moreover, the decomposition temperature of these three types MA/nano-TiO2/carbon additives composites is around 245 °C. Therefore, the working ambient temperature of MA/nano-TiO2/additive composites should be lower than 245 °C.



中文翻译:

肉豆蔻酸/​​纳米TiO2/碳添加剂复合相变材料的合成及热性能

采用熔融共混法合成了一种新型复合相变材料——肉豆蔻酸(MA)/纳米二氧化钛(nano-TiO 2)/碳添加剂,其中MA为相变材料,纳米TiO 2为添加剂。支撑材料和碳添加剂用作导热增强剂。一系列泄漏测试表明,当MA/纳米TiO 2中MA的含量不超过50%时,MA/纳米TiO 2在相变过程中能够保持形状稳定性。FT-IR和XRD结果表明MA/纳米TiO 2 /碳添加剂的各组分之间没有发生化学反应。当MA含量为50%时,MA/纳米TiO 2 /碳添加剂的熔融温度约为54℃,熔融焓约为80J·g -1。当多壁碳纳米管、石墨烯和膨胀石墨三种碳添加剂的含量均为2.5 %时,MA/纳米TiO 2 /碳添加剂相应的导热系数为0.532 W/(m·K)、1.128 W/分别为(m·K)和1.382 W/(m·K)。这三种MA/纳米TiO 2 /添加剂的导热系数分别是MA/TiO 2的1.23、2.62和3.21倍。此外,这三种MA/纳米TiO 2 /碳添加剂复合材料的分解温度约为245℃。因此,MA/纳米TiO 2 /添加剂复合材料的工作环境温度应低于245℃。

更新日期:2024-03-03
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