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Phenylglycine amphiphile-metal ion chiral supramolecular nanozymes for enantioselective catalysis
Chemical Communications ( IF 4.9 ) Pub Date : 2024-03-28 , DOI: 10.1039/d4cc00637b
Dongying Li 1 , Cong Gao 1 , Cici Zhao 1 , Qingqing Sun 1 , Zheng Xi 1 , Jie Han 1 , Rong Guo 1
Affiliation  

L/D-Phenylglycine amphiphiles and metal ions with peroxidase-like activity self-assembled into chiral nanoribbons, which act as efficient chiral supramolecular nanozymes for catalyzing the 3,4-dihydroxy-L/D-phenylalanine (L/D-DOPA) oxidation reactions. The catalytic efficiency and enantioselectivity are dominated by the chirality transfer and the synergistic effect between the metal ions and chiral nanoribbons.

中文翻译:

用于对映选择性催化的苯甘氨酸两亲金属离子手性超分子纳米酶

L / D-苯甘氨酸两亲物和具有类过氧化物酶活性的金属离子自组装成手性纳米带,作为高效的手性超分子纳米酶催化3,4-二羟基-L / D-苯丙氨酸(L / D -DOPA)氧化反应。催化效率和对映选择性主要由手性转移以及金属离子和手性纳米带之间的协同效应决定。
更新日期:2024-03-28
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